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Polymer Photodegradation : mechanisms and experimental methods - Semantic Scholar
On the other hand, the intensity of excimer and monomer fluorescence bands maxima was also found to decrease with increase in irradiation times. These changes may be attributed to the formation of new photoproducts resulted from the photodegradation of irradiated polymeric chains. The decrease in polarity of used solvents caused a considerable enhancement to the intensity of the polymer fluorescence band and accelerated photodegradation. A proposed mechanism is suggested to account for the effects of added plasticizers, the increase in irradiation time, and polarity of solvents on photodegradation and photooxidation processes in polymeric chains.
Introduction The irradiation effects on stability of polystyrene [1—5] and substituted polystyrene [6—10] in solutions have been extensively studied by both theoretical and experimental approaches.
The irradiation effect of halogenated polymers received a considerable attention, owing mainly to their industrial importance [11—13].