Manual Polymer Photodegradation: Mechanisms and experimental methods

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Anika Zafiah, Material properties of novelty polyurethane based on vegetable oils. Anika Zafiah, Effect of titanium dioxide on material properties for renewable rapeseed and sunflower polyurethane, International Journal of Integrated Engineering, Vol.

Polymer Photodegradation

Mohid, M. Anika Zafiah, and N. Anika Zafiah, S. Nurulsaidatulsyida, D. Talib, and T.

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Chattopadhyay and K. Raju, Structural engineering of polyurethane coatings for high performance applications, Progress Polymer Sciences, Vol. Arana, TiO2 - photocatalysis as a tertiary treatment of naturally treated wastewater, Catalysis Today, Vol.

Dillert, J. Engela and D. Hager, Photocatalytic oxidation of gaseous chlorinated organics over titanium dioxide, Chemosphere, Vol. Hitchman and F. Tian, Studies of TiO2 thin films prepared by chemical vapour deposition for photocatalytic and photoelectrocatalytic degradation of 4-chlorophenol, Journal of Electroanal Chemosphere, Vol.

Tham, and Willem, H.

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Zhang, X. Hu and Z. Luo, Wavelength sensitivity of photo-oxidation of polypropylene, Polymer Degradation and Stability, Vol. Kaczmarek, and A. Podgorski, Photochemical and thermal behaviors of poly Vinyl alcohol graphite oxide composite. Polymer Degradation and Stability, Vol. White, and A. Shyichuk, Effect of stabilization on scission and cross-linking rate changes during photo-oxidation of polypropylene, Polymer Degradation and Stability, Vol. Fechine, M. Rabello, and R.


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Polymer Photodegradation : mechanisms and experimental methods - Semantic Scholar

On the other hand, the intensity of excimer and monomer fluorescence bands maxima was also found to decrease with increase in irradiation times. These changes may be attributed to the formation of new photoproducts resulted from the photodegradation of irradiated polymeric chains. The decrease in polarity of used solvents caused a considerable enhancement to the intensity of the polymer fluorescence band and accelerated photodegradation. A proposed mechanism is suggested to account for the effects of added plasticizers, the increase in irradiation time, and polarity of solvents on photodegradation and photooxidation processes in polymeric chains.

Introduction The irradiation effects on stability of polystyrene [1—5] and substituted polystyrene [6—10] in solutions have been extensively studied by both theoretical and experimental approaches.

The irradiation effect of halogenated polymers received a considerable attention, owing mainly to their industrial importance [11—13].